Clay Mineralogy Exercise #4

1. Calculate the structural formula for the two samples below given the respective major elemental oxide analysis. Report your work assuming 11 oxygen equivalents per half unit cell. Show all your work.

2. Determine the tetrahedral, octahedral and interlayer layer charges for each sample.

 Sample A  phengitic muscovite  Sample B  vermiculite
 SiO2   46.50  SiO2  41.56
 TiO2   0.15  TiO2  0.47
 Al2O3   33.30  Al2O3  16.77
 Fe2O3  <0.01  Fe2O3  10.48
 FeO   0.20  FeO   0.90
 MnO  <0.01  MnO  0.35
 CaO  <0.01  CaO  4.63
 MgO  3.72  MgO  23.21
 K2O  9.87  K2O  0.19
 Na2O  <0.01  Na2O  0.06